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1

Od Marii Skłodowskie-Curie do współczesnych technologii radiacyjnyc

100%
Głuszewski W., Zagórski Z. P.
Kwartalnik Historii Nauki i Techniki
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2012
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vol. 57
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issue 1
71-88
EN
The article was written on the occasion of the 100. anniversary of the Nobel Prize in Chemistry awarded to Maria Skłodowska-Curie. The United Nations General Assembly honoured this event by announcing the year 2011 the International Year of Chemistry. Maria Skłodowska-Curie was i.a. the initiator of radiation chemistry, a branch of science analyzing the chemical effects that matter shows when exposed to ionizing radiation. The development of this branch resulted in radiation technologies` applications in many fields of industry, medicine, agriculture, protection of the environment, space research and science. Our point of departure was the article Sur l`étude des courbes de probabilité relatives à l`action des rayons X sur les bacilles that Maria Skłodowska-Curie published in 1929 in the Bulletin of the Académie des sciences. In this study, she presented - for the first time ever - the curves of the so called radiation inactivation, i.e. the relationship between the bacteria life expectancy and the dose of radiation absorbed by it. From the today`s point of view, it can be stated that the researcher laid the foundations of the methods of radiation sterilization and material processing by means of radiation. In this context, we recall the history of the first accelerator installation devised and built in 1968 at the Institute of Nuclear Chemistry and Technology in Warsaw. Basing on experiences with the linear electron accelerator, the LAE 13/9 was completed in 1992 as the so far only Polish industrial installation for radiation sterilization of medical products and transplants as well as for food irradiation.
2

Maria Skłodowska-Curie – jej chemia w setną rocznicę drugiej Nagrody Nobla

88%
Zagórski Z. P., Kornacka E.
Kwartalnik Historii Nauki i Techniki
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2012
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vol. 57
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issue 1
39-70
EN
The article presents from the perspective of one hundred years the work of Maria Curie-Skłodowska, which in many cases was ahead of the state of knowledge of the time. It opened new horizons and for this reason we made many digressions. The fact of awarding her the Nobel Prize twice is a sensation enough to present the values of careful activity of the Nobel Prize Committee that emphasizes the importance of Maria's achievements. A significant element of Maria Skłodowska-Curie's achievements was still mysterious character of the radiation in her time, and only chemical approach made it possible to organise the phenomena and explain the origin of the radiation. The essence of the research was an arduous separation of components following the track of growing radiation of successive fractions of preparations. This research was a start of the technology of educement of dispersed elements in great mass of materials. We underline the paramount role of the chemical research Maria Skłodowska conducted while still in Warsaw in the laboratories of the Museum of Industry and Agriculture under the guidance of an excellent chemist Józef Jerzy Boguski. Her research in Paris was the origin of the semi-commercial scale in chemistry and setting aside a special shed outside the university building was the beginning of the institutes that now function beyond universities and are key element of scientific and technical progress. Technology of splitting developed by Maria Skłodowska-Curie was applied also by other radiochemists, e.g. By Otto Hahn. Lively movement in radiochemistry of her lifetime resulted in Maria's disputes with e.g. German chemist Marckwald, who questioned the originality of polonium. The scientific disputes like this one Maria won triumphantly although in several others she had to accept opponents' argument, as in the case of radon. Her experiments were planned with utmost rationality as it was with the rejection of the hypothesis saying that radioactivity was transferred from the outer space or from the sun. A great part of Maria Skłodowska-Curie's work was connected with biology which was demonstrated by describing in mathematical terms, for the first time in the history of radiobiology, nonexistent at that time, of the phenomenon of inactivation of bacteria by ionizing radiation. We emphasize difficult conditions for the health of the radiochemists of the time but we don’t find any proof that there was any influence of ionizing radiation on Maria’s health. She must have absorbed much greater doses of radiation during her heroic work in the mobile radiological surgery at the front of the 1st World War. We don’t think it’s appropriate to speculate rashly about contamination with alpha emitters. Unfortunately, due to her family’s protest it was impossible to collect samples of remains before their relocation to the Pantheon in Paris.
3

Chemia analityczna w pracach Marii Skłodowskiej-Curie

75%
Hulanicki A.
Kwartalnik Historii Nauki i Techniki
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2012
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vol. 57
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issue 1
9- 22
EN
Maria Skłodowska-Curie – a Nobel Prize winner in chemistry – the elements of learning of chemistry gained just by a dint of work of more than ten months in Warsaw in the Institute of Industry and Agriculture Museum. The Nobel Prize concerned a contribution to the progress of chemistry through the discovery of radium and polonium, separation of radium and study of properties of this amazing element. It was awarded for an extremely arduous work, during which the chemical reactions being the principles of analytical chemistry were realized. Unlike to a typical analytical procedure, an initial attempt here was the thousands of kilograms of uranium ore: pitchblende. The final effect was small amounts of new elements: polonium and radium. Both the knowledge and the intuition of the researcher let her have a triumph. The difficulties she experienced because the properties of the searched chemical elements could only be evaluated thanks to the knowledge on other chemical elements. A significant achievement was the determination of the samples by means of radioactivity measurement, which gave rise to radiochemical analytical methods. An extreme analytical precision was demanded in multiple processes of fractional crystallization and precipitation which finally led to the calculation of the atomic mass of radium
4

Maria Skłodowska-Curie i Pierre Curie w epokowym roku 1898

63%
Wielogórski Z.
Kwartalnik Historii Nauki i Techniki
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2012
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vol. 57
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issue 1
23-38
EN
For many reasons the year 1898 was unusual for Maria Skłodowska-Curie and her husband. After defining the subject of the doctoral thesis and choosing Henri Becqerel as thesis supervisor, Maria started intensive experimental work. In the allotted room called storeroom, in conditions that were far too inadequate, they managed to put up a unique measuring equipment composed of instruments whose originator was Pierre Curie. In the ionization chamber and in the piezoelectric quartz charges formed, whose mutual neutralization was shown by the quadrant electrometer. Ionization current, which was measured quantitatively, was proportional to the radiation of the sample. Studying many elements, their compounds and minerals enabled Maria to state that uranium is not the only element endowed with the power of radiation; the second one turned out to be thorium. Anomaly detected in the radiation of uranium minerals made it possible for Maria to draw an extremely important conclusion: radioactive uranium and thorium are not the only elements endowed with such an attribute. Pitchblende, which was studied by the Curie couple, had to contain also other radioactive substances. Gustave Bémont also participated in the chemical analysis of the uranium ore and it is worth reminding that he was involved in the discovery of polonium and uranium. The phenomenon of radioactivity couldn’t have been explained if it was not for the sources of strong radioactivity. Those sources undoubtedly could have been the discovered elements but their scanty content in the uranium ore made their isolation very difficult and laborious. Access to industrial remains after procession of pitchblende from Jachymov (Sankt Joachimstahl), obtained owing to the mediation of Eduard Suess, provided the source of this raw material. From it, in a shack also called le hangar , the Curie couple isolated the first samples of the radium salt. This element, later extracted by discoverers on a grand scale and handed over in a various forms to researchers and institutions, became a foundation of physics and chemistry of radioactive elements.
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